华东师范大学学报(自然科学版) ›› 2006, Vol. 2006 ›› Issue (5): 116-120.

• 物理学 电子科学与技术 • 上一篇    下一篇

PS/CNTs复合材料中CNTs作用的研究

石 岩, 李相美, 何为凡, 徐学诚   

  1. 华东师范大学 纳米功能材料与器件应用研究中心,上海 200062
  • 收稿日期:2004-11-12 修回日期:2005-01-12 出版日期:2006-09-25 发布日期:2012-11-27

Study on Effects of CNTs in PS/CNTs Composites

SHI Yan, LI Xiang-mei, HE Wei-fan, XU Xue-cheng   

  1. Center of Functional Nanomaterials and Devices, East China Normal University,Shanghai 200062,China
  • Received:2004-11-12 Revised:2005-01-12 Online:2006-09-25 Published:2012-11-27

摘要： 利用悬浮聚合法制备了聚苯乙烯/碳纳米管复合材料.通过透射电镜观察到复合材料中CNTs包裹于PS粒子中，且PS粒子较纯PS粒子变大，并由动态光散射测试得到了证实.热重分析表明复合材料中PS最大失重速度时的温度较纯PS升高了约80 ℃.GPC的测定也反映出复合材料中PS的分子量较纯PS有较大幅度的提高.据此可以认为：在悬浮聚合法中，CNTs参与了PS的聚合反应，与PS形成了键合并使PS的聚合程度增加.

关键词: 聚苯乙烯/碳纳米管复合材料, 透射电镜, 动态光散射, 热重分析, 凝胶渗透色谱 ,  ,

Abstract: PS/CNTs were prepared by a simple suspension polymerization method. TEM images showed that CNTs are wrapped in PS particles which are larger than pure PS particles, and it can be proved by DLS tests. TGA showed that the temperature of maximum speed on loss in weight of PS in composites is 80 ℃ higher than that of pure PS. And GPC tests also showed that the molecular weight of PS in composites is much higher than that of pure PS. So the CNTs have joined the polymerization of PS and bonded with PS which lead to an increase in polymerization extent of PS.

Key words: PS/CNTs composites, TEM, DLS, TGA, GPC  ,

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