缓释氧材料在河湖水体污染修复中的应用研究进展

doi:10.3969/j.issn.1000-5641.2024.01.002

华东师范大学学报（自然科学版） ›› 2024, Vol. 2024 ›› Issue (1): 9-16.doi: 10.3969/j.issn.1000-5641.2024.01.002

• 水环境评价与修复治理 • 上一篇下一篇

缓释氧材料在河湖水体污染修复中的应用研究进展

曹洋¹, 顾敦罡^1,*(), 李光辉¹, 黄民生^2,³, 何文辉⁴

1. 上海工程技术大学化学化工学院, 上海　201620
2. 华东师范大学生态与环境科学学院, 上海　200241
3. 华东师范大学上海市城市化生态过程与生态恢复重点实验室, 上海　200241
4. 上海太和水科技发展股份有限公司, 上海　201702

收稿日期:2023-02-24 接受日期:2023-04-23 出版日期:2024-01-25 发布日期:2024-01-23
通讯作者: 顾敦罡 E-mail:dgu@sues.edu.cn
基金资助:
上海市科委项目(20DZ2250700); 上海市科委地方院校能力建设专项计划(21010501400); 上海市城市化生态过程与生态恢复重点实验室开放基金(SHUES2023A05)

A review on the application of slow-release oxygen materials in the remediation of polluted rivers and lakes

Yang CAO¹, Dungang GU^1,*(), Guanghui LI¹, Minsheng HUANG^2,³, Wenhui HE⁴

1. School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai　201620, China
2. School of Ecological and Environmental Sciences, East China Normal University, Shanghai　200241, China
3. Shanghai Key Lab for Urban Ecological Processes and Eco-Restoration, East China Normal University, Shanghai　200241, China
4. Shanghai Taihe Water Technology Development Co. Ltd., Shanghai　201702, China

Received:2023-02-24 Accepted:2023-04-23 Online:2024-01-25 Published:2024-01-23
Contact: Dungang GU E-mail:dgu@sues.edu.cn

摘要/Abstract

摘要：

投加增氧剂作为一种提升水体溶解氧的重要手段常用于城市水环境的治理与修复, 研发具有缓释效果的增氧材料可使增氧剂在实际工程中更持久、更稳定地发挥作用. 本文梳理了近年来缓释氧材料的制备方法和释氧性能, 综述了投加缓释氧材料对河湖沉积物和上覆水中营养盐等污染物赋存形态与迁移转化的影响及作用机制, 最后对缓释氧材料在河湖水体污染修复中的应用研究提出了展望和建议.

关键词: 缓释氧材料, 制备方法, 沉积物–水界面, 营养盐

Abstract:

Oxygen-releasing materials are often used in the treatment and restoration of urban waters as an important method to enhance dissolved oxygen. The development of materials with slow-release property can improve the durability and stability of oxygen release in practical engineering. This paper reviews the preparation methods and oxygen release performance of the slow-release oxygen materials reported in recent years. Moreover, the effects and mechanisms of slow-release oxygen materials on the occurrence, migration, and transformation of pollutants such as nutrients in sediments and overlying water of rivers and lakes are reviewed. Finally, prospects and suggestions for the application of slow-release oxygen materials in the remediation of rivers and lakes are proposed.

Key words: slow-release oxygen materials, preparation, sediment-water interface, nutrients

中图分类号:

曹洋, 顾敦罡, 李光辉, 黄民生, 何文辉. 缓释氧材料在河湖水体污染修复中的应用研究进展[J]. 华东师范大学学报（自然科学版）, 2024, 2024(1): 9-16.

Yang CAO, Dungang GU, Guanghui LI, Minsheng HUANG, Wenhui HE. A review on the application of slow-release oxygen materials in the remediation of polluted rivers and lakes[J]. Journal of East China Normal University(Natural Science), 2024, 2024(1): 9-16.

图/表 2

表1

表2

参考文献 49

1	吴闪闪, 刘付文晓, 许志国, 等.. 硝酸钙缓释颗粒原位修复黑臭底泥的作用机制及其应用. 环境工程学报, 2022, 16 (7): 2198- 2207.
2	范成新, 刘敏, 王圣瑞, 等.. 近 20 年来我国沉积物环境与污染控制研究进展与展望. 地球科学进展, 2021, 36 (4): 346- 374.
3	雷沛, 张洪, 王超, 等.. 沉积物水界面污染物迁移扩散的研究进展. 湖泊科学, 2018, 30 (6): 1489- 1508.
4	李乾岗, 田颖, 刘玲, 等.. 水体中沉积物氮和磷的释放机制及其影响因素研究进展. 湿地科学, 2022, 20 (1): 94- 103.
5	LIU Z, BAI G, LIU Y, et al.. Long-term study of ecological restoration in a typical shallow urban lake. Science of the Total Environment, 2022, 846, 157505.
6	DONG Z, WANG Y, FU J, et al.. Benthic ecological restoration under the combined action of slow-release oxygen material and benthic organisms. Chemosphere, 2022, 301, 134658.
7	ZHU J, HE Y, WANG J, et al.. Impact of aeration disturbances on endogenous phosphorus fractions and their algae growth potential from malodorous river sediment. Environmental Science and Pollution Research, 2017, 24 (9): 8062- 8070.
8	TANG C, LI Y, HE C, et al.. Dynamic behavior of sediment resuspension and nutrients release in the shallow and wind-exposed Meiliang Bay of Lake Taihu. Science of the Total Environment, 2020, 708, 135131.
9	郭雅倩, 薛建辉, 吴永波, 等.. 沉水植物对富营养化水体的净化作用及修复技术研究进展. 植物资源与环境学报, 2020, 29 (3): 58- 68.
10	李锋民, 陈琳, 姜晓华, 等.. 水质净化与生态修复的水生植物优选指标体系构建. 生态环境学报, 2021, 30 (12): 2411- 2422.
11	黄靖宇, 徐佳, 李传龙, 等.. 缓释氧剂的制备及其在黑臭水体治理方面的应用研究. 现代化工, 2018, 38 (12): 165- 169.
12	李亮, 武成辉, 林翰志, 等.. 复合释氧剂的制备及其对水体修复的作用. 环境工程, 2017, 35 (9): 1- 6.
13	李亮, 武成辉, 陈涛, 等.. 过氧化钙在城镇黑臭水体修复中的作用. 化工进展, 2016, 35 (S2): 340- 346.
14	王锋, 董文艺, 王宏杰, 等.. CaO₂原位处理河道黑臭底泥效能研究. 环境工程, 2020, 38 (12): 64- 69.
15	WANG H, ZHAO Y, LI T, et al.. Properties of calcium peroxide for release of hydrogen peroxide and oxygen: A kinetics study. Chemical Engineering Journal, 2016, 303, 450- 457.
16	李明, 朱晓明, 阮晓红, 等.. 包裹缓释外壳的缓释氧材料的性能影响分析. 地下水, 2012, 34 (6): 173- 175.
17	薛栋, 丁爱中, 朱宜, 等.. 应用于黑臭水体的新型缓释氧材料制备及其释氧效果模拟. 环境工程, 2019, 37 (9): 57- 61.
18	郭鹏飞, 董子义, 王颖, 等.. 缓释氧复合材料不同投加方式对沉积物–水界面污染物迁移的影响. 环境工程, 2021, 39 (5): 1- 8.
19	LEE C S, LE THANH T, KIM E J, et al.. Fabrication of novel oxygen-releasing alginate beads as an efficient oxygen carrier for the enhancement of aerobic bioremediation of 1, 4-dioxane contaminated groundwater. Bioresource Technology, 2014, 171, 59- 65.
20	ZHOU Y, FANG X, ZHANG Z, et al.. An oxygen slow-releasing material and its application in water remediation as oxygen supplier. Environmental Technology, 2017, 38 (22): 2793- 2799.
21	殷瑶, 朱煜.. 过氧化钙缓释氧颗粒的制备及缓释氧过程调控. 净水技术, 2019, 38 (S1): 199- 203.
22	刘涉江, 刘秀丽, 王少博.. CPC/CaO₂氧缓释复合材料的制备及其释氧性能探讨. 环境工程学报, 2010, 4 (5): 971- 974.
23	周彦波, 王英秀, 周振华, 等.. 过氧化钙缓释氧剂的制备及其释氧特性研究. 中国给水排水, 2012, 28 (7): 64- 67.
24	WU C H, CHANG S H, LIN C W.. Improvement of oxygen release from calcium peroxide-polyvinyl alcohol beads by adding low-cost bamboo biochar and its application in bioremediation. Clean-Soil Air Water, 2015, 43 (2): 287- 295.
25	夏德春, 郑翔, 吕树光, 等.. 过氧化钙缓释材料对河道水固磷及底泥控磷的机理研究. 环境污染与防治, 2020, 42 (5): 553- 557.
26	UTECH S, BOCCACCINI A R.. A review of hydrogel-based composites for biomedical applications: Enhancement of hydrogel properties by addition of rigid inorganic fillers. Journal of Materials Science, 2016, 51 (1): 271- 310.
27	YANG J, LIN F K, YANG L, et al.. A bench-scale assessment for phosphorus release control of sediment by an oxygen-releasing compound (ORC). Journal of Environmental Science and Health, Part A, 2015, 50 (1): 49- 59.
28	朱煜.. 过氧化钙缓释氧剂对微生物降解苯系物的强化效能和机理研究. 应用化工, 2020, 49 (4): 916- 920.
29	杨丽, 廖传华, 朱跃钊, 等.. 微纳米气泡特性及在环境污染控制中的应用. 化工进展, 2012, 31 (6): 1333- 1337.
30	LYU T, WU S, MORTIMER R J G, et al.. Nanobubble technology in environmental engineering: Revolutionization potential and challenges. Environmental Science & Technology, 2019, 53 (13): 7175- 7176.
31	WANG J, CHEN J, YU P, et al.. Oxygenation and synchronous control of nitrogen and phosphorus release at the sediment-water interface using oxygen nano-bubble modified material. Science of the Total Environment, 2020, 725, 138258.
32	PAN G, HE G, ZHANG M, et al.. Nanobubbles at hydrophilic particle–water interfaces. Langmuir, 2016, 32 (43): 11133- 11137.
33	YU P, WANG J, CHEN J, et al.. Successful control of phosphorus release from sediments using oxygen nano-bubble-modified minerals. Science of the Total Environment, 2019, 663, 654- 661.
34	苗肖君, 陈俊, 王蕾, 等.. 氧微纳气泡改性矿物对水体的增氧效果及机理. 环境保护科学, 2019, 45 (6): 44- 52.
35	LI Y, XIONG X, ZHANG C, et al.. Sustainable restoration of anoxic freshwater using environmentally-compatible oxygen-carrying biochar: Performance and mechanisms. Water Research, 2022, 214, 118204.
36	ZHANG H, LYU T, BI L, et al.. Combating hypoxia/anoxia at sediment-water interfaces: A preliminary study of oxygen nanobubble modified clay materials. Science of the Total Environment, 2018, 637, 550- 560.
37	WANG L, MIAO X, ALI J, et al.. Quantification of oxygen nanobubbles in particulate matters and potential applications in remediation of anaerobic environment. ACS Omega, 2018, 3 (9): 10624- 10630.
38	李诗月, 冯丽娟, 武华杰, 等.. 氧纳米气泡改性活性炭在河道底泥氨氮治理中的应用. 科学技术与工程, 2021, 21 (19): 8283- 8289.
39	TANG Y, ZHANG M, ZHANG J, et al.. Reducing arsenic toxicity using the interfacial oxygen nanobubble technology for sediment remediation. Water Research, 2021, 205, 117657.
40	余萍萍. 氧纳米气泡改性颗粒对深水沉积物–水界面的增氧效果及环境效应研究 [D]. 贵阳: 贵州大学, 2019.
41	PAN X, LIN L, HUANG Z, et al.. Distribution characteristics and pollution risk evaluation of the nitrogen and phosphorus species in the sediments of Lake Erhai, Southwest China. Environmental Science and Pollution Research, 2019, 26 (22): 22295- 22304.
42	LI X, SONG J, YUAN H, et al.. Biogeochemical characteristics of nitrogen and phosphorus in Jiaozhou Bay sediments. Chinese Journal of Oceanology and Limnology, 2007, 25 (2): 157- 165.
43	HOU D, HE J, LU C, et al.. Spatial variations and distributions of phosphorus and nitrogen in bottom sediments from a typical north-temperate lake, China. Environmental Earth Sciences, 2014, 71 (7): 3063- 3079.
44	李雨平, 姜莹莹, 刘宝明, 等.. 过氧化钙(CaO₂)联合生物炭对河道底泥的修复. 环境科学, 2020, 41 (8): 3629- 3636.
45	WANG F, WANG H, ZHAO Z, et al.. Simultaneous elimination of black-odor and stabilization of heavy metals in contaminated sediment using calcium peroxide/hydroxyapatite: Microbial responses and ecotoxicological effects. Journal of Hazardous Materials, 2022, 429, 128298.
46	徐垚, 李大鹏, 韩菲尔, 等.. CaO₂不同投加方式对黑臭河道底泥内源磷释放抑制作用. 环境科学, 2017, 38 (7): 2836- 2842.
47	韩琦, 薛爽, 刘影, 等.. 河流底泥中溶解性有机物的释放途径及影响因素研究. 中国环境科学, 2016, 36 (12): 3737- 3749.
48	NYKANEN A, KONTIO H, KLUUTAS O, et al.. Increasing lake water and sediment oxygen levels using slow release peroxide. Science of the Total Environment, 2012, 429, 317- 324.
49	张钟慧. CaO₂控制沉积物–水界面内源氮磷释放的微生物群落响应机制研究 [D]. 西安: 西安建筑科技大学, 2020.

材料组成	水体 DO 的改善效果	水体 pH 值	参考文献
CaO₂-水泥-河沙-黄糊精	35 d 内提升至 5.8 mg·L^–1	8 ~ 9	[17]
CaO₂-白土-水泥	100 h 内提升至 8 mg·L^–1	9 ~ 10	[18]
CaO₂-海藻酸钠	7 d 内提升至 3 mg·L^–1 以上	11	[19]
CaO₂-硬脂酸	18 d 内维持在 4 mg·L^–1以上	7 ~ 8	[20]
CaO₂-PHA	100 h 内维持在 2.5 mg·L^–1	8.43	[21]
CaO₂-磷酸钙骨水泥	45 h 内提升至 5 mg·L^–1	7.4	[22]
CaO₂-石英砂-硬脂酸	42 d 内保持在 5 mg·L^–1左右	7.2 ~ 7.6	[23]
CaO₂-PVA-生物炭	70 d 内维持在 2 mg·L^–1以上	7.5	[24]
CaO₂-PEG2000-硬脂酸	35 d 内保持在 5 mg·L^–1以上	9 ~ 10	[25]

载体	负载方法	水体 DO 改善效果	参考文献
白云母	醇水替换法	1 d 内最高提升至 9 mg·L^–1	[33]
凹凸棒石、蒙脱石	真空变压吸附法	72 h 内分别提升至 4.6 mg·L^–1和 4.4 mg·L^–1	[34]
沉积物基生物炭	真空变压吸附法	28 d 内维持在 4.78 mg·L^–1以上	[35]
沸石、土壤	真空变压吸附法	127 d 内维持在 4 ~ 7.5 mg·L^–1	[36]
硅藻土	温度梯度法	120 d 内维持在 5 mg·L^–1左右	[37]
活性炭	真空变压吸附法	24 h 内提升至 6 mg·L^–1	[38]
沸石	真空变压吸附法	20 d 内维持在 3 ~ 4 mg·L^–1	[39]

[1]	李志福, 吴永红, 刘雪梅, 李丹. 基于稻虾共作系统水稻收割后水体水质及沉积物重金属风险评估[J]. 华东师范大学学报（自然科学版）, 2024, 2024(1): 122-133.
[2]	杨安强, 赵丽侠, 宋淑贞, 刘倢, 何彦龙, 王艳娜. 赤潮异弯藻对CO₂浓度、温度和营养盐变化的响应[J]. 华东师范大学学报（自然科学版）, 2023, 2023(3): 108-117.
[3]	袁育鑫, 刘佳敏, 潘玲, 王丽红, 张雪俐, 黄民生. 纳米材料在藻华控制方面的应用与研究进展[J]. 华东师范大学学报（自然科学版）, 2021, 2021(4): 90-98.
[4]	同萌, 李茂田, 牛淑杰, 刘晓强, 林沐东, 郭慧婷, 候立军. 长江流域水库叶绿素及营养盐变化: 生物过滤器效应[J]. 华东师范大学学报（自然科学版）, 2021, 2021(2): 63-72.
[5]	王丰毅，陆健健. 胭脂鱼（Myxocyprinus asiaticus）幼鱼在河口区的生存适应性实验研究[J]. 华东师范大学学报(自然科学版), 2012, 2012(1): 19-26.
[6]	邓可;杨世伦;刘素美;张经. 长江口崇明东滩冬季沉积物水界面营养盐通量[J]. 华东师范大学学报(自然科学版), 2009, 2009(3): 17-27.

缓释氧材料在河湖水体污染修复中的应用研究进展

A review on the application of slow-release oxygen materials in the remediation of polluted rivers and lakes

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 2

参考文献 49

相关文章 6

编辑推荐

Metrics

本文评价