生物基2,5-呋喃二甲酸的绿色合成技术综述

doi:10.3969/j.issn.1000-5641.2023.01.016

摘要/Abstract

摘要：

生物基芳香二酸2,5-呋喃二甲酸 (2,5-furandicarboxylic acid, FDCA) 有望部分替代石油基二酸对苯二甲酸 (terephthalic acid, PTA) 用于高性能高分子材料的合成. 本文综述了从5-羟甲基糠醛 (5-hydroxymethylfurfural, HMF)、糠酸、呋喃、二甘醇酸、己糖二酸、2,5-二甲基呋喃和2-甲基呋喃制备FDCA的各路线, 并详细介绍了HMF的直接氧化法、多相热催化氧化法、光电催化氧化法以及糠酸羧基化、歧化、羰基化等策略合成FDCA. 在比较了各路线优缺点的基础上, 认为HMF路线和糠酸路线是FDCA规模化生产最有希望的路线, 提出未来应在改进催化路线、简化反应工艺、提高分离效率、减少三废含量等方面进行更为深入的探索和研究.

关键词: 2,5-呋喃二甲酸, 生物质, 5-羟甲基糠醛, 糠酸, 绿色合成

Abstract:

Bio-based 2,5-furandicarboxylic acid (FDCA) is expected to partially replace petroleum-based terephthalic acid (PTA) for the synthesis of high-performance polymer materials. This review article summarizes the latest achievements on the various synthesis routes of FDCA from 5-hydroxymethylfurfural (HMF), furoic acid, furan, diglycolic acid, hexaric acid, 2,5-dimethylfuran, and 2-methylfuran. In particular, the direct oxidation, heterogeneous thermal catalytic oxidation, photoelectric catalytic oxidation of HMF and furoic acid carboxylation, disproportionation, carbonylation, and other routes to synthesize FDCA are reviewed in detail. Based on the comparative analysis of the advantages and disadvantages of each route, the HMF route and the furoic acid route are considered the most promising candidates for the large-scale production of FDCA. Further exploration and future research should be carried out to improve the catalytic production and separation efficiency of FDCA, simplify the reaction process, and reduce production wastes.

Key words: 2,5-furandicarboxylic acid, biomass, 5-hydroxymethylfurfural, furoic acid, green synthesis

中图分类号:

O643

赵磊, 李泽霖, 李愽龙, 边树昌, 王建华, 张海兰, 赵晨. 生物基2,5-呋喃二甲酸的绿色合成技术综述[J]. 华东师范大学学报（自然科学版）, 2023, 2023(1): 160-169.

Lei ZHAO, Zelin LI, Bolong LI, Shuchang BIAN, Jianhua WANG, Hailan ZHANG, Chen ZHAO. Comprehensive review on green synthesis of bio-based 2,5-furandicarboxylic acid[J]. Journal of East China Normal University(Natural Science), 2023, 2023(1): 160-169.

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