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Aminocarbonylation of propylene (ethylene) epoxide over Co2(CO)8 catalyst modified by bidental O-containing ligand for synthesis of β-hydroxy amides
Received date: 2022-06-21
Accepted date: 2022-09-16
Online published: 2023-01-07
This work reports a one-step protocol for the synthesis of β-hydroxyamides via amino-carbonylation of epoxides using aromatic amines as the ammonia source instead of silylamine. The reaction was catalyzed by Co2(CO)8 modified with bidentate O-containing ligand L2, which was prepared by the oxidation of Xantphos [9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene] by H2O2 as a diphosphine-dioxide. Under mild conditions (60 °C, CO 3.0 MPa, 6 h), L2-modified Co2(CO)8 efficiently catalyzed the amino-carbonylation of propylene oxide with aniline to generate 3-hydroxy-N-phenylbutanamide with the yield of 64%. The developed catalytic system exhibited fair stability and general substrate scope.
Key words: propylene oxide; ethylene oxide; aminocarbonylation; Co2(CO)8; β-hydroxy amides
Lin GUO , Guanghui SHI , Xiaochao CHEN , Ye LIU . Aminocarbonylation of propylene (ethylene) epoxide over Co2(CO)8 catalyst modified by bidental O-containing ligand for synthesis of β-hydroxy amides[J]. Journal of East China Normal University(Natural Science), 2023 , 2023(1) : 12 -20 . DOI: 10.3969/j.issn.1000-5641.2023.01.002
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