Journal of East China Normal University(Natural Sc ›› 2003, Vol. 2003 ›› Issue (1): 74-80.
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DAI Li-yi; SHAN Yong-kui; HE Ming-yuan
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Abstract: In this paper, a serie of multicomponent substitued polyoxometalate clusters containing silicon, tungsten, molybdenum and earlier transition metal elements were synthesized. The genetal moleculat formulat was determined: K4H2[M(OH2)SiMo2W9O39].nH2O (M=Mn2+,Co2+,Ni2+,Cu2+, Zn2+, Cd2+; n=21-26). By means of IR,UV,XPS,TG-DTA, the properties and structural characteristics of the new tungstomolybdosilic multicomponent polyoxometalate clusters with transition elements were investigated.
Key words: tungstomolybdosilicate, transition elements , polyoxometalate clusters, tungstomolybdosilicate, transition elements
DAI Li-yi;SHAN Yong-kui;HE Ming-yuan. Synthesis and Properties of Tungstomolybdosilic Multicomponent Polyoxometalate Clusters with Transition Elements[J]. Journal of East China Normal University(Natural Sc, 2003, 2003(1): 74-80.
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