Journal of East China Normal University(Natural Sc ›› 2009, Vol. 2009 ›› Issue (2): 122-128.

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Influences of different oxidants on the structure and properties of Poly(otoluidine) synthesized by interfacial polymerization （Chinese）

Arzugul·Muslim, Abduwayiti·Yusufu, Ayimnisa·Abdukerim
  

  1. School of Life Science and Chemistry, Xinjiang Normal University， Urumqi 830054， China
  • Received:2008-03-03 Revised:2008-10-13 Online:2009-03-25 Published:2009-03-25
  • Contact: Arzugul·Muslim

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Abstract:

Poly(otoluidine) was synthesized by interfacial polymerization using iron chloride, ammonium persulfate, and a complex (composed by K2S2O8, CuSO4 and NaHSO3) as oxidant, respectively. The molecular structures,morphologies and electrochemical behaviors were detected by FTIR, UVVIS, SEM and Cyclic voltammetry. The results showed that poly(otoluidine) particles appeared as micro powder and their diameters were within several hundred nanometers. All the three polymers showed good electrochemical activity. When using FeCl3 as oxidant, the molecular weight and conjugated degree, as well as the electrochemical activity of the poly(otoluidine), were the best.

Key words: oxidant, facial synthesis, poly(otoluidine), oxidant, facial synthesis

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