Journal of East China Normal University(Natural Sc ›› 2010, Vol. 2010 ›› Issue (4): 131-136.

• Article • Previous Articles    

Study on the synthesis,crystal structure and thermal stability of [Zn(IBG)(H2O)3]·2H2O

XU Han1, LI Yi-zhi2   

  1. 1. Department of Chemistry, Huangshan University, Huangshan Anhui 245041, China; 2. State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
  • Received:2009-04-01 Revised:2009-08-01 Online:2010-07-25 Published:2010-07-25
  • Contact: XU Han

Abstract: The complex [Zn(IBG)(H2O)3]·2H2O (H2IBG= isophthaloylbisglycine) was synthesized and its crystal structure was characterized by X-ray diffraction. The compound crystallizes in orthorhombic crystal system, space group C222(1), with Mr=431.65,a=0.693 01(14) nm,b=0.772 56(14) nm,c=23.006 4(6) nm, V=1.609 61 nm^-3,Z=4,Dc=1.781 g·cm^-3,F(000)=888.0. The molecular structures are stabilized by hydrogen bonds. The title compound was measured by IR, thermogravimetric analysis and XRD.

Key words: hydrogen bonds, XRD, Zn coordination complex: crystal structure, hydrogen bonds, XRD

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