Catalytic asymmetric synthesis of chiral heterocyclic compounds with CO2 as the C1 synthon

doi:10.3969/j.issn.1000-5641.2023.01.004

Abstract

Abstract:

As the main component of greenhouse gases, CO₂ represents an inexpensive and readily available renewable C1 synthon. In the past few decades, great efforts have been made toward the development of chemical processes that use CO₂ as a promising fossil fuel alternative for C1 feedstocks for the production of industrially attractive chemicals. This could provide access to materials of commercial interest from an abundant, nontoxic, renewable, and low-cost carbon source, thus offering interesting opportunities for the chemical industry, organic synthesis, and so on. Considering the importance of chiral heterocycles in organic synthesis and drug development, the development of highly stereoselective and efficient catalytic asymmetric reactions using CO₂ as a C1 synthon for these chiral heterocycles has received considerable attention. Successful examples for chiral lactones, carbonates, and carbamates have already been demonstrated. In this paper, we summarize the recent advances in this field.

Key words: carbon dioxide, catalytic asymmetric synthesis, chiral heterocyclic compounds

CLC Number:

O626

Zhipeng ZHAO, Ying SUN, Xiaotong GAO, Feng ZHOU. Catalytic asymmetric synthesis of chiral heterocyclic compounds with CO₂ as the C1 synthon[J]. Journal of East China Normal University(Natural Science), 2023, 2023(1): 31-40.

Figures/Tables 12

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Catalytic asymmetric synthesis of chiral heterocyclic compounds with CO₂ as the C1 synthon

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